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A one-pot organocatalytic process for the synthesis of cyclic carbonates from CO2 and alkenes using cumene hydroperoxide as a green oxidant

A one-pot organocatalytic process for the synthesis of cyclic carbonates from CO2 and alkenes using cumene hydroperoxide as a green oxidant

by ICIQ | Mar 3, 2026 | Research Output

Angelo Scopano – DC5 Cyclic carbonates are usually obtained from coupling of carbon dioxide and epoxides. The latter are generally prepared through the selective oxidation of alkenes or other compounds containing a double bond. However, a one-pot route in which...
Solvent-Free Synthesis of Renewable FDCA-based Bis-Cyclic Carbonate Using a Metal-Free Heterogeneous Catalyst

Solvent-Free Synthesis of Renewable FDCA-based Bis-Cyclic Carbonate Using a Metal-Free Heterogeneous Catalyst

by ICIQ | Feb 19, 2026 | Research Output

Giovanni Berluti – DC6 In this work, we developed a new, fully renewable catalytic strategy to synthesise an industrially relevant bio-based cyclic carbonate: 2,5-bis-dicarboxyl furan cyclic carbonate (BDFCC). This compound contains two terminal cyclic carbonate...
CO2/epoxides ring-opening copolymerization towards hydroxy-functionalized polycarbonates

CO2/epoxides ring-opening copolymerization towards hydroxy-functionalized polycarbonates

by ICIQ | Feb 4, 2026 | Research Output

  Nishant Chaudhary – DC8 Ring-opening copolymerization (ROCOP) of CO2 and epoxides witnesses continued interest to access sustainable polycarbonates. Introduction of an exocyclic functional group onto the epoxides enables to tune and diversify the...
Domino Synthesis of Functionalized Cyclic Acetals From Organic Carbonates

Domino Synthesis of Functionalized Cyclic Acetals From Organic Carbonates

by ICIQ | Nov 14, 2025 | Research Output

Natalia Kulbacka – DC2 We report a method for the base-mediated transformation of ether-tethered acrylic ester-based cyclic carbonates into functionalized cyclic acetals. The protocol builds on the use of hydroxyalkyl-substituted cyclic carbonates that undergo...
Enabling a Diversity-Oriented Catalytic Atom Looping of a Biobased Polycarbonate

Enabling a Diversity-Oriented Catalytic Atom Looping of a Biobased Polycarbonate

by ICIQ | Oct 6, 2025 | Research Output

Enrico Lanaro – DC1 Herein, it is demonstrated that biobased poly(menthene carbonate) (PMC) can be conveniently used to enable catalysis-promoted atom looping thereby creating functionalized synthons and new types of repolymerizable monomers. The biobased...
Palladium-catalyzed methoxycarbonylation of a commodity CO2-sourced δ-valerolactone

Palladium-catalyzed methoxycarbonylation of a commodity CO2-sourced δ-valerolactone

by ICIQ | Jul 18, 2025 | Research Output

Hussein Tabaja – DC7 The methoxycarbonylation of 3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one (EVP), a commodity δ-valerolactone prepared by telomerization of CO2 with butadiene, is reported. The pytbpx ligand proved instrumental to achieve successful formation...

Recent Posts

  • Sara Faoro and Angelo Scopano took part in the European Researchers’ Night in Tarragona
  • Giovanni started at CiTOS: Center for Integrated Technology and Organic Synthesis
  • Lilas starts her secondment at Polykey
  • Angelo Scopano presented the project at the IV Open Forum on Arts, Science & Technology
  • The D-Carbonize doctoral candidates present their ongoing research at the Industry Workshop in Heidelberg

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